1982
DOI: 10.1071/ch9820351
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Constituents of Boesenbergia pandurata (syn. Kaempferia pandurata): Isolation, Crystal Structure and Synthesis of (±)-Boesenbergin A

Abstract: Partly racemized pinostrobin and pinocembrin, together with 2',6'-dihydroxy-4'-methoxychalcone, cardamonin and a new chalcone (�) boesenbergin A, have been isolated from Boesenbergia pandurata Schl. (syn. Kaempferia pandurata Roxb., Zingiberaceae). Spectroscopic studies and X-ray crystallographic analysis have established the structure (�)-(E)-1-[7'-hydroxy-5'-methoxy-2'-methyl- 2'-(4''-methylpent-3''-enyl)-2'H-chromen-8'-yl]-3-phenylprop-2-enone for boesenbergin A. A simple synthesis of boesenbergin A has bee… Show more

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Cited by 70 publications
(50 citation statements)
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“…Those nine compounds from the pulp and five compounds from the seeds of S. samarangense were identified by the spectroscopic methods and HPLC-PDA analysis with authentic standards (Figure 1 2′,4′-Dihydroxy-3′-methyl-6′-methoxychalcone (stercurensin) (2): yellow-orange crystals (3.9 mg) ( (Jaipetch et al, 1982).…”
Section: Isolation and Purificationmentioning
confidence: 99%
“…Those nine compounds from the pulp and five compounds from the seeds of S. samarangense were identified by the spectroscopic methods and HPLC-PDA analysis with authentic standards (Figure 1 2′,4′-Dihydroxy-3′-methyl-6′-methoxychalcone (stercurensin) (2): yellow-orange crystals (3.9 mg) ( (Jaipetch et al, 1982).…”
Section: Isolation and Purificationmentioning
confidence: 99%
“…Chemical structures were established using standard techniques of IR, UV, 1H-NMR and 13C-NMR, and mass spectroscopy which were compared with the spectroscopic data in the literature (Nilsson 1961 ;Hayashi et al 1969;Bohlmann et al 1977;Bohlmann & Abraham 1979;Cooksey et al 1982;Jaipetch et al 1982;Tanaka et al 1984;Burke & Nair 1986). 2,4,6'-trihydroxychalcone, 2,6'-dihydroxy-4'-methoxychalcone, and 1-(5-acetyl-2-hydroxyphenyl)-3-methyl-2-buten-1-one Air dried leaves and stems of O. leptophyllus (100 g) were extracted by steeping with 600 ml portions of dichloromethane/ methanol (1:3) over four successive days (Fig.…”
Section: Chemicalmentioning
confidence: 99%
“…1969;Hayashietal. 1970;Bohm 1975;Bohlmann et al 1980;Cooksey et al 1982;Jaipetch et al 1982;Wollenweber 1982;Burke & Nair 1986;Bohm 1988), 2',4',6'-trihydroxychalcone (Bohlmann & Abraham 1979;Bohlmann et al 1980;New Zealand Journal of Botany, 1999, Vol.37 '-(5'-Acetyl-2'-hydroxyphenyl)-3-methyl-2-buten-l-one Bohlmann et al 1982;Proksch et al 1983;), 2',4'-dihydroxy-4'-methoxydihydrochalcone (Goris & Chanal 1935;Nilsson 1961;Star 1980;Tanakaetal. 1984), and 1'-(5'-acetyl-2'-hydroxyphenyl)-3-methyl-2-buten-l-one (Bohlmann et al 1977).…”
Section: IImentioning
confidence: 99%
“…Spectroscopic characterization: 5-Hydroxy-7-methoxyflavanone (Pinostrobin) [14] : Crystals: Colorless needles from EtOH m.p. 100.8-101.6 °C (Lit.…”
Section: Odoratamentioning
confidence: 99%