Constitution of Asphaltic Bitumen. Characterization of Bitumens by a Combination of Pyrolysis, Hydrogenation, and Gas-Liquid Chromatography

Knotnerus, J.

doi:10.1021/i360021a008

Cited by 5 publications

(1 citation statement)

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“…Currently, the definition of asphaltenes is based on their solubility behavior in n -alkanes ( n -C 5 – n -C 7 ); however, there have been efforts to establish a molecular definition of asphaltenes based on structure and function. − Early works began in the 1950s, with the development of standard methodologies to precipitate asphaltenes from crude oils and bitumen. − Current efforts are focused on unraveling asphaltenes’ molecular architecture with the goal of predicting reactivity of heavy oils in upgrading processes, adsorption of asphaltenic material on mineral surfaces, and asphaltene deposition …”

Section: Introductionmentioning

confidence: 99%

Exploring Occluded Compounds and Their Interactions with Asphaltene Networks Using High-Resolution Mass Spectrometry

et al. 2016

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In this contribution, we use high-resolution mass spectrometry to unveil the molecular composition of occluded compounds inside Colombian asphaltenes macrostructures. We use Soxhlet extraction, with n-heptane, coupled with asphaltene maceration to obtain four fractions enriched with chemical compounds occluded inside asphaltene networks. We focused our efforts on the fraction enriched with compounds interacting with asphaltenes via strong intermolecular forces, and used normal phase column chromatography to fractionate it and atmospheric pressure photoionization coupled to Fourier transform ion cyclotron resonance mass spectrometry to obtain a detailed molecular description. Our results indicate that the occluded compounds obtained in the last stage of the washing process are by themselves a complex mixture, consisting mostly of saturated compounds including molecular formulas corresponding to biomarkers, alkyl aromatics with high heteroatom content (up to four heteroatoms), vanadyl porphyrins, and highly aromatic species, which we believe are low-molecular weight asphaltenes transferred to the n-heptane during the extraction process. We consider this information valuable because analysis of occluded compounds gives us a more thorough molecular description of asphaltenes; besides, knowledge of compounds closely related to asphaltenes could not only improve deasphalting processes in pilot plants, but also will help to find new geochemical biomarkers occluded within asphaltenes.

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