It is important but difficult to study the constitutive equations describing the mechanical properties of steels. In this work, a thermal/mechanical simulator was used in conjunction with the Anand model to obtain the stress-strain curves for a high chromium steel associated with different temperature/strain rate pairs. The finite element software, ANSYS, was used to simulate the stress-strain behavior of a high chromium steel during casting at the strain rates of 1, 0.1, and 0.01 1/s, and to validate the Anand model. The results show that the high-temperature deformation is mainly plastic and the von Mises stresses are small, the stresses introduced at elevated temperatures have little effect on the residual stress fields, and the simulation of the mechanical behavior of steels using an elastic-plastic model at low temperatures during cooling is acceptable.