With the development of modern power systems, the number of remote inspection robots in substations is gradually increasing. This study aims to achieve collaborative scheduling of dual machine operations for remote inspection robots in substations to improve inspection efficiency and reduce operating costs. By constructing a kinematic model of the inspection robot, the kinematic characteristics of the inspection robot are obtained. A master-slave system-based collaborative scheduling method for dual machine operations of remote inspection robots in substations is proposed, which includes the principle of closest distance and the maximum behavior value coordination strategy to realize collaborative scheduling of dual machine operations for inspection robots. Through experimental verification and evaluation, it has been found that the proposed method can significantly improve obstacle avoidance and load balancing capabilities, achieve maximum resource utilization, and effectively shorten the robot operation path, providing more reliable and efficient support for the operation and maintenance of substations.