Calcium chloride hexahydrate(CaCl 2 •6H 2 O) composites PCMs containing strontium chloride hexahydrate (SrCl 2 •6H 2 O) and oxidation expandable graphite(EGO) were prepared and phase change behavior of CaCl 2 •6H 2 O/EGO/SrCl 2 •6H 2 O composite PCMs, including supercooling degree, phase change temperature, latent heat, density, thermal conductivity and thermal stability were systematically studied. Results demonstrate that thermal conductivity, heat transfer and the latent capacities of the CaCl 2 •6H 2 O/SrCl 2 •6H 2 O/EGO composite PCMs are significantly enhanced, supercooling of CaCl 2 •6H 2 O/SrCl 2 •6H 2 O/EGO composite PCMs are suppressed, mainly ascribe to that the EGO are homogenously dispersed in PCMs due to the existence of oxygen-containing functional groups in EGO, meanwhile, the well-dispersed EGO serving as nuclei to promote the heterogeneous nucleation and crystallization process of CaCl 2 •6H 2 O. Moreover, a fifty-run-cycling test verifies that the CaCl 2 •6H 2 O/SrCl 2 •6H 2 O/EGO composites PCMs contained with 3wt.% SrCl 2 •6H 2 O, and 1.0wt.% EGO possesses enhanced thermal behavior with no phase segregation observed; the latent heat was calculated to be 172.26 J/g.