Construction Archimedean tiling patterns based on soft materials from block copolymers and covalent organic frameworks

Enhanced thermal and porous properties of double-decker-shaped polyhedral silsesquioxane-bismaleimide (DDSQ-BMI) nanocomposites for high-performance CO2 storage and supercapacitors

“…11–15 The various POPs are produced by synthetic approaches that incorporate conjugated microporous polymers (CMP), covalent organic frameworks (COF), covalent triazine frameworks, and hyper-crosslinked polymers (HCP), and they are constructed using imine, azine, imide and triazine linkages. 16–20…”

Controllable Wet-Brush Blending of Linear Diblock Copolymers with Phenolic/DDSQ Hybrids toward Mesoporous Structure Phase Diagram

“…Self-assembled structures such as typical lamella (LAM), hexagonal packing cylinder (HPC), sphere, double gyroid (DG), and even special Frank–Kasper phases of immiscible diblock copolymers (BCP) have been widely investigated during recent years because of their potential applications including soft lithography, photonic crystals, nanocomposites, and mesoporous materials. − The synthetic strategies of BCP with composition and structural variety are mainly from sequential addition of monomer through controlled living polymerization techniques or coupling reactions from the active chain ends with two different polymer chains. − It is well-known that the self-assembled structures are primarily dependent on the volume fraction, interaction parameter (χ), and degree of polymerization ( N ); however, mediating the volume fraction is complicated and time-consuming through the controlled living polymerization . As a result, blending homopolymer (A or B) into an A- b -B diblock copolymer is a relatively simpler method to mediate different self-assembled structures for varying volume fractions …”

Strategic Design and Synthesis of Ferrocene Linked Porous Organic Frameworks toward Tunable CO2 Capture and Energy Storage

“…Various POP structures incorporating covalently linked linkages, such as boroxine, triazine, hydrazine, imide, and imine units, have been synthesized using chemical reactions like Suzuki, Sonogashira, Schiff base formation, Heck, Yamamoto, and Friedel couplings [38][39][40][41][42][43][44]. POPs can be categorized into several materials, including COFs, CMPs, PIMs, HCPs, and CTFs [45][46][47][48]. These diverse categories demonstrate the versatility and potential of POPs for various applications, highlighting their importance in the development of advanced materials for addressing environmental concerns and energy-related challenges.…”