Construction of Cd(II) complexes based on 2-(1H-imidazol-1-methyl)-1H-benzimidazole and 1,4-benzenedicarboxylate

Crystal structure of catena-poly[diaqua(μ2-2-(hydroxymethyl)-1H-imidazole-4,5-dicarboxylato)cadmium(II)], C6H8CdN2O7

“…Each Cd1 ion is six-coordinated and located in a distorted octahedral CdN 2 O4 coordination environment formed by two N atoms (N1 and N2#1) and two O atoms (O4#1 and O5) from two H 2 hmIDC 2− anions and by two water molecules (O6 and O7). The Cd-O bond lengths range from 2.357(2) to 2.535(2) Å and the Cd-N bond lengths are 2.207(2) and 2.254(2) Å, respectively; these values are within the normal ranges and close to those reported in other Cd(II) complexes [13][14][15]. Cd(II) ions are linked by H 2 hmIDC 2− ligand into one-dimensional chains that run along the c axis.…”

Synthesis and Structure Elucidation of Two Essential Metal Complexes: In-Vitro Studies of Their BSA/HSA-Binding Properties, Docking Simulations, and Anticancer Activities

“…Furthermore, relatively strong π-π interactions can be found between the tetrazole rings of adjacent layers. In complex 2, the distance between two adjacent centroids is 3.4909(10) Å, which is within the normal range for π-π interactions [35][36][37]. Similar to complex 2, the centroid-centroid distance is 3.4977(12) Å in complex 1.…”

Crystal structure of catena-poly[triqua-bis(μ 2-4-carboxy-2-(1H-tetrazol-1-yl)-1H-imidazole-5-carboxylato-k3 N,O:O′)barium(II)] tetrahydrate, C14H14BaN12O15

“…There are O-H … O intramolecular hydrogen bonds between carboxyl and carboxylate groups, and O-H … O, O-H … N and N-H … O inter molecular hydrogen bonds involving carboxylate groups, imidazole ring, tetrazole ring, coordination water molecules and solvent water molecules. In addition, there are π-π stacking interactions between imidazole rings of adjacent chains with a centroid-centroid distance of 3.5699(7) Å, which is in the range for common π-π interactions [15][16][17]. Adjacent chains are linked by the aforementioned hydrogen bonds and π-π interactions, to a three-dimensional architecture in the solid state.…”