“…The bond valence method was rst used to analyze inorganic crystal structures [32][33][34][35][36] and was gradually applied in other elds. [37][38][39][40][41] It can be traced back historically to a proposal by Pauling. 42 It is a classic and valid approach for assessing the charge between a metal atom and its bound coordinated atoms, and has proved an effective method to evaluate the electron density in a delocalized system 43 and the oxidation states of metals in a metalloprotein.…”
Iron valences of 129 P-clusters from FeMo/V proteins were analyzed using a bond valence method, supposing the existence of Fe3+ in a generally considered all-ferrous PN cluster in solution with excess reducing agent.
“…The bond valence method was rst used to analyze inorganic crystal structures [32][33][34][35][36] and was gradually applied in other elds. [37][38][39][40][41] It can be traced back historically to a proposal by Pauling. 42 It is a classic and valid approach for assessing the charge between a metal atom and its bound coordinated atoms, and has proved an effective method to evaluate the electron density in a delocalized system 43 and the oxidation states of metals in a metalloprotein.…”
Iron valences of 129 P-clusters from FeMo/V proteins were analyzed using a bond valence method, supposing the existence of Fe3+ in a generally considered all-ferrous PN cluster in solution with excess reducing agent.
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