Construction of stable Zn metal anode by inorganic functional protective layer toward long-life aqueous Zn-ion battery

Zhao, Lu-Lu; Zhao, Shan; Zhang, Nan; Wang, Peng-Fei; Liu, Zong-Lin; Xie, Ying; Shu, Jie; Yi, Ting-Feng

doi:10.1016/j.ensm.2024.103628

Energy Storage Materials

2024

DOI: 10.1016/j.ensm.2024.103628

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Construction of stable Zn metal anode by inorganic functional protective layer toward long-life aqueous Zn-ion battery

Lu-Lu Zhao,

Shan Zhao,

Nan Zhang

et al.

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Cited by 2 publications

References 136 publications

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An Ionic Sieve‐Integrated Conductive Interfacial Design to Simultaneously Regulate the Zn²⁺ Flux and Interfacial Resistance for Advancing Zinc‐Ion Batteries

Wang,

Wu,

Xie

et al. 2024

Adv Funct Materials

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Zinc‐ion batteries possess operation safety, high energy density, production flexibility and affordability, making them attractive for scalable energy storage. While Zn anodes face significant challenges from rampant dendrite growth and electrolyte‐related side‐reactions in a complex interfacial microenvironment. The growing interfacial resistance further degrades the battery performance. An integrated anode interfacial design is reported to regulate simultaneously the Zn2+ flux and interfacial resistance through in situ confinement growth of Zn2+ sieve, that is, 2D CuBDC metal–organic framework in mesoporous carbonaceous host. CuBDC with sub‐nanometer channels is selected for efficient dehydration and directional Zn2+ flux transport, and lowering the nucleation barrier by zincophilic Cu(II) and N sites. Conductive meso‐carbon reduces the interfacial resistance and blocks the interfacial side‐reactions. Resultantly, the modified Zn anodes demonstrate improved cycling stability with lower voltage polarization, supported by operando optical microscopy and ex situ analysis. This work provides a feasible strategy improving aqueous Zn anodes and new interfacial insights on designing advancing zinc batteries.

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An Ionic Sieve‐Integrated Conductive Interfacial Design to Simultaneously Regulate the Zn²⁺ Flux and Interfacial Resistance for Advancing Zinc‐Ion Batteries

Wang,

Wu,

Xie

et al. 2024

Adv Funct Materials

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In situ polymerization of poly(3,4-ethylenedioxythiophene) protective layer towards stable zinc anode

Luo,

Zhou,

et al. 2025

Nano Research

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Construction of stable Zn metal anode by inorganic functional protective layer toward long-life aqueous Zn-ion battery

Cited by 2 publications

References 136 publications

An Ionic Sieve‐Integrated Conductive Interfacial Design to Simultaneously Regulate the Zn²⁺ Flux and Interfacial Resistance for Advancing Zinc‐Ion Batteries

An Ionic Sieve‐Integrated Conductive Interfacial Design to Simultaneously Regulate the Zn²⁺ Flux and Interfacial Resistance for Advancing Zinc‐Ion Batteries

In situ polymerization of poly(3,4-ethylenedioxythiophene) protective layer towards stable zinc anode

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Construction of stable Zn metal anode by inorganic functional protective layer toward long-life aqueous Zn-ion battery

Cited by 2 publications

References 136 publications

An Ionic Sieve‐Integrated Conductive Interfacial Design to Simultaneously Regulate the Zn2+ Flux and Interfacial Resistance for Advancing Zinc‐Ion Batteries

An Ionic Sieve‐Integrated Conductive Interfacial Design to Simultaneously Regulate the Zn2+ Flux and Interfacial Resistance for Advancing Zinc‐Ion Batteries

In situ polymerization of poly(3,4-ethylenedioxythiophene) protective layer towards stable zinc anode

Contact Info

Product

Resources

About

An Ionic Sieve‐Integrated Conductive Interfacial Design to Simultaneously Regulate the Zn²⁺ Flux and Interfacial Resistance for Advancing Zinc‐Ion Batteries

An Ionic Sieve‐Integrated Conductive Interfacial Design to Simultaneously Regulate the Zn²⁺ Flux and Interfacial Resistance for Advancing Zinc‐Ion Batteries