Construction of Supramolecular Assemblies Based on Anion–π Interactions

Bauzá, Antonio

doi:10.1002/9781119113874.ch11

Non‐covalent Interactions in the Synthesis and Design of New Compounds 2016

DOI: 10.1002/9781119113874.ch11

|View full text |Cite

Construction of Supramolecular Assemblies Based on Anion–π Interactions

Antonio Bauzá

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 121 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Dominant Metal-NCIs Stabilizing Crystal Packing in Silver(I)-Pyridyl Compounds: Insights from Crystallographic and Computational Studies

Theunissen,

Esterhuysen,

Bourne

2024

Crystal Growth & Design

View full text Add to dashboard Cite

This study analyzes the structural and interaction properties of silver(I) compounds with benzoate (OBn) (I) and various neutral pyridyl ligands, specifically pyridine (py), 2chloropyridine (2-Clpy), 3-chloropyridine (3-Clpy) (II), 2-picoline (2-Pic) (III), 2-bromopyridine (2-Brpy) (IV), and 2-iodopyridine (2-Ipy) (V). Using single-crystal X-ray diffraction, we determined the crystal structures of five compounds, revealing distinct molecular geometries (planar vs bent). For the noncrystallizing [Ag 2 (OBn) 2 (py) 2 ] and [Ag 2 (OBn) 2 (2-Clpy) 2 ] systems, computational models were constructed to explore their potential structures. We assessed the roles of metal-involved interactions�Agand Ag + •••X(C), where X = Br or I�in crystal packing. Quantum theory of atoms in molecules (QTAIM) and natural bond orbital (NBO) analyses provided further insights into these interactions. In compounds I, II, and III, Ag + •••Ag + and Ag + •••(C) aromatic interactions were the primary preorganizing factors. In contrast, bromine and iodine substituents in compounds IV and V introduced additional stability via uncommon Ag + •••X(C) semicoordination interactions, replacing Ag + •••(C) aromatic interactions.

show abstract

Dominant Metal-NCIs Stabilizing Crystal Packing in Silver(I)-Pyridyl Compounds: Insights from Crystallographic and Computational Studies

Theunissen,

Esterhuysen,

Bourne

2024

Crystal Growth & Design

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Construction of Supramolecular Assemblies Based on Anion–π Interactions

Cited by 1 publication

References 121 publications

Dominant Metal-NCIs Stabilizing Crystal Packing in Silver(I)-Pyridyl Compounds: Insights from Crystallographic and Computational Studies

Dominant Metal-NCIs Stabilizing Crystal Packing in Silver(I)-Pyridyl Compounds: Insights from Crystallographic and Computational Studies

Contact Info

Product

Resources

About