Bipolar materials, which work as both the cathode and anode materiali na queous sodium-ionb atteries, have advantages over aqueous electrolytes such as the low cost of sodium and high convenience of the material processing. However,t he availablem aterials are greatly limited. Herein, Prussian blue FeFe(CN) 6 nanocubesw ere successfully synthesized by using a modifiedc o-precipitation method. Owingt ot he well-separated redox reactions, fair cycling stability and rate capability of FeFe(CN) 6 ,i tc ould be developed as ab ipolar material in an aqueous sodium-ion battery.T he as-obtained full battery exhibits good cycling stabilitya nd rate capability.I tw as ablet o deliver ac apacity of 32 mA hg À1 at 20 C, 76 %o ft he capacity at 2C.A fter 200 cycles at 2C,9 7% of the initial capacity was maintained for this battery,which suggests good cycling stability.