Construction of three-dimensional polymeric d-histidine based metal-organic framework (MOF) for selective sorption of CO2 and copper ion sensing applications

A highly robust cluster-based indium(iii)–organic framework with efficient catalytic activity in cycloaddition of CO2 and Knoevenagel condensation

“…S8†). It is worth mentioning that the Q st value of NUC-66a surpasses the most recently reported MOFs, such as FUT-1 (22.5 kJ mol −1 ) and DHTZn (20.47 kJ mol −1 ), 50,51 but lower than the ones of MOF-505 (32 kJ mol −1 ), (Me 2 NH 2 ) 1.5 (Ln 1.5 L 2 )·2DMF·2H 2 O (31 kJ mol −1 ) and [Zn 3 (BINDI)(DATRZ) 2 (H 2 O) 2 ] n (45 kJ mol −1 ), 52–54 indicating that CO 2 adsorbed in NUC-66a is easy to release and regenerate.…”

“…To clarify the affinity between CO 2 and NUC-66a, the isothermal heat of CO 2 adsorption (Q st ) was calculated to be 25. [52][53][54] indicating that CO 2 adsorbed in NUC-66a is easy to release and regenerate.…”

Robust {Pb10}-Cluster-Based Metal–Organic Framework for Capturing and Converting CO2 into Cyclic Carbonates under Mild Conditions

“…In addition, with the consumption of coal, oil, and natural gas, the greenhouse effect mainly caused by the released byproduct carbon dioxide (CO 2 ) has caused a series of environmental problems, seriously disrupting the normal and sustainable development of humans. , Therefore, the urgent problem that needs to be solved now is how to reduce CO 2 emissions in various industrial production processes and achieve minimization of the global climate impact. In order to achieve a sustainable low-carbon economy, carbon capture and separation (CCS) is currently considered an effective technology to reduce CO 2 emissions from fossil fuel combustion, especially in the fields of power generation and industry. , At present, power plants mainly use various types of alkanolamine alkaline liquids to capture CO 2 in the flue gas of the power plant with an efficiency of up to 98% .…”

Iron Oxide Nanoparticle-Assisted Delamination of Ti3C2Tx MXenes: A New Approach to Produce Magnetic MXene-Based Composites

“…We study how exactly the growth of MNPs in the solution affects the stacking between neighboring MXene sheets, thoroughly investigate the magnetic properties of the obtained nanocomposite materials, and show their applicability in water remediation technologies by studying their adsorption capacity towards Cu 2+ in water. Cu is a toxic heavy metal, whose short- and long-term acute exposure causes food poisoning, gastrointestinal illness, nausea, and the disruption of homeostasis in the human liver [ 49 , 50 , 51 , 52 , 53 , 54 , 55 ]. According to the World Health Organization (WHO), an acceptable limit for Cu 2+ in the drinking water is 1.5 mg/L [ 56 ], and its presence above the specified limit must be eliminated.…”