Construction of β-Oximino Phosphorodithioates via (2,2,6,6-Tetramethylpiperidin-1-yl)oxyl-Promoted Difunctionalization of Alkenes with tert-Butyl Nitrite, P4S10, and Alcohols

Chen, Xiao-ming; Huang, Jian; Pan, Jun; Xie, Yi; Zeng, Fei; Wei, Wei; Yi, Dong

doi:10.1021/acs.orglett.4c01038

Org. Lett.

2024

DOI: 10.1021/acs.orglett.4c01038

|View full text |Cite

Construction of β-Oximino Phosphorodithioates via (2,2,6,6-Tetramethylpiperidin-1-yl)oxyl-Promoted Difunctionalization of Alkenes with tert-Butyl Nitrite, P₄S₁₀, and Alcohols

Xiao-ming Chen,

Jian Huang,

Jun Pan

et al.

Abstract: Published as part of Organic Letters virtual special issue "Radical Reactions for the Construction and Transformation of Complex Molecules".

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article4

Relationship

Self Cite0

Independent4

Authors

Journals

Cited by 4 publications

References 57 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Visible-light-induced photocatalyst- and metal-free radical phosphinoyloximation of alkenes with tert-butyl nitrite as bifunctional reagent

Yang,

Li,

Zhang

et al. 2024

Chinese Chemical Letters

View full text Add to dashboard Cite

Visible-light-induced photocatalyst- and metal-free radical phosphinoyloximation of alkenes with tert-butyl nitrite as bifunctional reagent

Yang,

Li,

Zhang

et al. 2024

Chinese Chemical Letters

View full text Add to dashboard Cite

Oxyphosphorodithiolation of Vinyl Azides with P₄S₁₀ and Alcohols Leading to β-Keto Phosphorodithioates

Huang,

Ma,

Sun

et al. 2024

J. Org. Chem.

View full text Add to dashboard Cite

A simple strategy for the synthesis of β-keto phosphorodithioates has been developed through the direct oxyphosphorodithiolation of vinyl azides with P 4 S 10 and alcohols in the presence of water. The reaction is conducted at room temperature to provide a number of β-keto phosphorodithioates in moderate to good yields. This methodology has the advantages of simple operation, mild condition, broad substrate scope, and favorable group compatibility.

show abstract

New Frontiers in phosphorothioate formation: harnessing inorganic phosphorus sources

He,

Zhou,

Wan

et al. 2024

Chem. Commun.

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Construction of β-Oximino Phosphorodithioates via (2,2,6,6-Tetramethylpiperidin-1-yl)oxyl-Promoted Difunctionalization of Alkenes with tert-Butyl Nitrite, P₄S₁₀, and Alcohols

Abstract: Published as part of Organic Letters virtual special issue "Radical Reactions for the Construction and Transformation of Complex Molecules".

Cited by 4 publications

References 57 publications

Visible-light-induced photocatalyst- and metal-free radical phosphinoyloximation of alkenes with tert-butyl nitrite as bifunctional reagent

Visible-light-induced photocatalyst- and metal-free radical phosphinoyloximation of alkenes with tert-butyl nitrite as bifunctional reagent

Oxyphosphorodithiolation of Vinyl Azides with P₄S₁₀ and Alcohols Leading to β-Keto Phosphorodithioates

New Frontiers in phosphorothioate formation: harnessing inorganic phosphorus sources

Contact Info

Product

Resources

About

Construction of β-Oximino Phosphorodithioates via (2,2,6,6-Tetramethylpiperidin-1-yl)oxyl-Promoted Difunctionalization of Alkenes with tert-Butyl Nitrite, P4S10, and Alcohols

Abstract: Published as part of Organic Letters virtual special issue "Radical Reactions for the Construction and Transformation of Complex Molecules".

Cited by 4 publications

References 57 publications

Visible-light-induced photocatalyst- and metal-free radical phosphinoyloximation of alkenes with tert-butyl nitrite as bifunctional reagent

Visible-light-induced photocatalyst- and metal-free radical phosphinoyloximation of alkenes with tert-butyl nitrite as bifunctional reagent

Oxyphosphorodithiolation of Vinyl Azides with P4S10 and Alcohols Leading to β-Keto Phosphorodithioates

New Frontiers in phosphorothioate formation: harnessing inorganic phosphorus sources

Contact Info

Product

Resources

About

Construction of β-Oximino Phosphorodithioates via (2,2,6,6-Tetramethylpiperidin-1-yl)oxyl-Promoted Difunctionalization of Alkenes with tert-Butyl Nitrite, P₄S₁₀, and Alcohols

Oxyphosphorodithiolation of Vinyl Azides with P₄S₁₀ and Alcohols Leading to β-Keto Phosphorodithioates