A disturbance observer-based hybrid sliding mode impedance control method is proposed in this paper, which is able to achieve robot end constant contact force-tracking control without force/torque sensors. The method requires only the values of joint torque, joint angle, and joint angular velocity, which are converted by robot servo motor signals, to implement the control. The control scheme consists of two parts: one is a disturbance observer and the other is a hybrid sliding mode impedance controller. The disturbance observer, which takes robot internal signals mentioned above as the inputs to estimate the robot end contact force, is designed based on generalized momentum, thus improving the estimation accuracy. The hybrid sliding mode impedance controller, which uses the values estimated by the disturbance observer and the robot internal signals as the inputs to calculate the corresponding position adjustment, integrates both the impedance control and sliding mode control, thus improving the force-tracking performance and robustness. Experimental results show that the proposed disturbance observer-based hybrid sliding mode impedance control method possesses high control precision.