Levoglucosan has
been widely used to quantitatively assess biomass
burning’s contribution to ambient aerosols, but previous such
assessments have not accounted for levoglucosan’s degradation
in the atmosphere. We develop the first global simulation of atmospheric
levoglucosan, explicitly accounting for its chemical degradation,
to evaluate the impacts on levoglucosan’s use in quantitative
aerosol source apportionment. Levoglucosan is emitted into the atmosphere
from the burning of plant matter in open fires (1.7 Tg yr–1) and as biofuels (2.1 Tg yr–1). Sinks of atmospheric
levoglucosan include aqueous-phase oxidation (2.9 Tg yr–1), heterogeneous oxidation (0.16 Tg yr–1), gas-phase
oxidation (1.4 × 10–4 Tg yr–1), and dry and wet deposition (0.27 and 0.43 Tg yr –1). The global atmospheric burden of levoglucosan is 19 Gg with a
lifetime of 1.8 days. Observations show a sharp decline in levoglucosan’s
concentrations and its relative abundance to organic carbon aerosol
(OC) and particulate K+ from near-source to remote sites.
We show that such features can only be reproduced when levoglucosan’s
chemical degradation is included in the model. Using model results,
we develop statistical parametrizations to account for the atmospheric
degradation in levoglucosan measurements, improving their use for
quantitative aerosol source apportionment.