2014
DOI: 10.5194/amt-7-1763-2014
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Continuous measurements of atmospheric water vapour isotopes in western Siberia (Kourovka)

Abstract: Abstract. The isotopic composition of atmospheric water vapour at the land surface has been continuously monitored at the Kourovka astronomical observatory in western Siberia (57.037° N, 59.547° E; 300 m a.s.l.) since April 2012. These measurements provide the first record of δD, δ18O and d-excess in this region. Air was sampled at 8 m height within a forest clearing. Measurements were made with a wavelength-scanned cavity ring-down spectroscopy analyzer (Picarro L2130-i). Specific improvements of the measurem… Show more

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Cited by 54 publications
(78 citation statements)
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“…4), with slopes lower than eight, a value attributed to thermodynamic equilibrium, as it approximately represents the average ratio between D and 18 O liquid-vapour equilibrium fractionation. Such low slopes have also been observed in atmospheric vapour from Hawaii (7.02 ), Greenland (between 6.47 and 7.44 (Steen-Larsen et al, 2013)), western Siberia (between 5.6 and 7.7 (Bastrikov et al, 2014)), and in North America (7.5 ). The previously described shift in d during Rayleigh-type rainout, due to the nonlinearity in the deuterium excess definition, is not sufficient to explain these low slopes, and non-equilibrium processes such as evaporation are also probably involved (Gibson et al, 2008).…”
Section: Regional Isotopic Signaturesmentioning
confidence: 87%
“…4), with slopes lower than eight, a value attributed to thermodynamic equilibrium, as it approximately represents the average ratio between D and 18 O liquid-vapour equilibrium fractionation. Such low slopes have also been observed in atmospheric vapour from Hawaii (7.02 ), Greenland (between 6.47 and 7.44 (Steen-Larsen et al, 2013)), western Siberia (between 5.6 and 7.7 (Bastrikov et al, 2014)), and in North America (7.5 ). The previously described shift in d during Rayleigh-type rainout, due to the nonlinearity in the deuterium excess definition, is not sufficient to explain these low slopes, and non-equilibrium processes such as evaporation are also probably involved (Gibson et al, 2008).…”
Section: Regional Isotopic Signaturesmentioning
confidence: 87%
“…However, on the northern Tibetan Plateau, the δ 18 O composition of water vapour and precipitation correlated positively with tem- perature (Yin et al, 2008). A positive correlation between the isotope record of water vapour and temperature (T ) was also found at Heidelberg (Germany), western Siberia, southern Greenland, and Minnesota (USA) (respectively, SchochFischer et al, 1984;Bastrikov et al, 2014;Bonne et al, 2014;Welp et al, 2008). Clearly, the relationships between δ 18 O-T and δ 18 O-RH at our station differ from those at other stations.…”
Section: The Effects Of Meteorological and Environmental Factors On δmentioning
confidence: 92%
“…However, at low humidity levels (<1500 ppmv) the instrument reveals a strong increase in uncertainty estimated to be 5.6 ‰ for δD and 0.92 ‰ for δ 18 O at 1000-1500 ppmv and 11.2 ‰ for δD and 1.84 ‰ for δ 18 O at 500-1000 ppmv (Bastrikov et al, 2014). The measurements below 500 ppmv are considered to be beyond the instrument measuring capabilities and are not used in the analysis.…”
Section: Water Vapor Measurements At Kourovkamentioning
confidence: 99%