Abstract. Droplet formation provides a direct microphysical link between aerosols and
clouds (liquid or mixed-phase), and its adequate description poses a major
challenge for any atmospheric model. Observations are critical for
evaluating and constraining the process. To this end, aerosol size
distributions, cloud condensation nuclei (CCN), hygroscopicity, and lidar-derived
vertical velocities were observed in alpine mixed-phase clouds during the
Role of Aerosols and Clouds Enhanced by Topography on Snow (RACLETS) field
campaign in the Davos, Switzerland, region during February and March 2019.
Data from the mountain-top site of Weissfluhjoch (WFJ) and the valley site
of Davos Wolfgang are studied. These observations are coupled with a
state-of-the-art droplet activation parameterization to investigate the
aerosol–cloud droplet link in mixed-phase clouds. The mean CCN-derived
hygroscopicity parameter, κ, at WFJ ranges between 0.2–0.3,
consistent with expectations for continental aerosols. κ tends to
decrease with size, possibly from an enrichment in organic material
associated with the vertical transport of fresh ultrafine particle emissions
(likely from biomass burning) from the valley floor in Davos. The
parameterization provides a droplet number that agrees with observations to
within ∼ 25 %. We also find that the susceptibility of
droplet formation to aerosol concentration and vertical velocity variations
can be appropriately described as a function of the standard deviation of
the distribution of updraft velocities, σw, as the droplet
number never exceeds a characteristic limit, termed the “limiting droplet
number”, of ∼ 150–550 cm−3, which depends solely on
σw. We also show that high aerosol levels in the valley, most likely from anthropogenic activities, increase the cloud droplet number, reduce cloud supersaturation (< 0.1 %), and shift the clouds to a state that is less susceptible to changes in aerosol concentrations and very sensitive to vertical velocity variations. The transition from an aerosol to velocity-limited regime
depends on the ratio of cloud droplet number to the limiting droplet number,
as droplet formation becomes velocity limited when this ratio exceeds 0.65.
Under such conditions, droplet size tends to be minimal, reducing the
likelihood that large drops are present that would otherwise promote
glaciation through rime splintering and droplet shattering. Identifying
regimes where droplet number variability is dominated by dynamical – rather
than aerosol – changes is key for interpreting and constraining when and
which types of aerosol effects on clouds are active.