Self-sustaining
smoldering combustion is a promising technology
for treating sewage sludge from wastewater treatment plants because
of its low energy inputs. Proper use or disposal of the resulting
ashes requires thorough characterization of their properties, including
the content of total organic carbon (TOC). Here, we develop a two-step
method for quantifying TOC in the raw ashes from sewage sludge smoldering
combustion. The first step is to thermally treat the raw ashes at
500 °C in N2 for 1 h, followed by ultimate analysis
of both the raw ashes and the thermally treated ashes. This enables
the quantification of carbon released during thermal treatment. The
second step is nonisothermal thermogravimetric analysis (TGA) of the
thermally treated ashes, in which the samples are heated to 900 °C
at 10 °C/min in air. The weight losses at 310–500 °C
are confirmed to be caused by organic carbon oxidation, allowing us
to determine the contents of carbon retained in the thermally treated
ashes. The sums of these two portions of carbon represent the contents
of TOC in the raw ashes, which are ∼0.85–6.52 wt % (dry
basis), depending on their locations and particle sizes. The two-step
(thermal treatment–TGA) method is validated via a method that
includes acid washing of the thermally treated ashes, ultimate analysis
of the acid-washed ashes, and TOC analysis of the leachates. The two-step
method is simple and accurate and, importantly, provides thorough
information on the thermal behavior of the raw and thermally treated
ashes.