This paper derives a measure of central counterparty (CCP) clearing-network risk that is based on the probability that the maximum exposure (the N-th order statistic) of a CCP to an individual general clearing member is large. Our analytical derivation of this probability uses the theory of Laplace asymptotics, which is related to the large deviations theory of rare events. The theory of Laplace asymptotics is an area of applied probability that studies the exponential decay rate of certain probabilities and is often used in the analysis of the tails of probability distributions. We show that the maximum-exposure probability depends on the topology, or structure, of the clearing network. We also derive a CCP's Maximum-Exposure-at-Risk, which provides a metric for evaluating the adequacy of the CCP's and general clearing members' loss-absorbing financial resources during rare but plausible market conditions. Based on our analysis, we provide insight into how clearing-network structure can affect the maximum-exposure risk of a CCP and, thereby, network stability. We show that the rate function (the exponential decay rate) of the maximumexposure probability is informative and can be used to compare the relative maximum-exposure risks across different network configurations.