Contrasting Magnetism in Isovalent Layered LaSr₃NiRuO₄H₄ and LaSrNiRuO₄ due to Distinct Spin-Orbital States*

Abstract

The recently synthesized first 4d transition-metal oxide-hydride LaSr3NiRuO4H4 with the unusual high H:O ratio surprisingly displays no magnetic order down to 1.8 K. This is in sharp contrast to the similar unusual low-valent Ni + -Ru 2+ layered oxide LaSrNiRuO4 which has a rather high ferromagnetic (FM) ordering Curie temperature TC ∼ 250 K. In this work, using density functional calculations with aid of crystal field level diagrams and superexchange pictures, we find that the contrasting magnetism is due to the distinct spin-orbital states of the Ru 2+ ions (in addition to the common Ni + S=1/2 state but with a different orbital state): the Ru 2+ S=0 state in LaSr3NiRuO4H4, but the Ru 2+ S=1 state in LaSrNiRuO4. The Ru 2+ S=0 state has the (xy) 2 (xz, yz) 4 occupation due to the RuH4O2 octahedral coordination, and then the nonmagnetic Ru 2+ ions dilute the S=1/2 Ni + sublattice which consequently has a very weak antiferromagnetic (AF) superexchange and thus accounts for no presence of magnetic order down to 1.8 K in LaSr3NiRuO4H4. In strong contrast, the Ru 2+ S=1 state in LaSrNiRuO4 has the (3z 2 − r 2 ) 2 (xz, yz) 3 (xy) 1 occupation due to the planar square RuO4 coordination, and then the multi-orbital FM superexchange between the S=1/2 Ni + and S=1 Ru 2+ ions gives rise to the high TC in LaSrNiRuO4. This work highlights the importance of spin-orbital states in determining the distinct magnetism.