Contrasting reactivity of B–Cl and B–H bonds at [Ni(IMes)<sub>2</sub>] to form unsupported Ni-boryls

Audsley, Gabrielle; Carpentier, Ambre; Pécharman, Anne-Frédérique; Wright, James; Roseveare, Thomas M.; Clark, Ewan R.; Macgregor, Stuart A.; Riddlestone, Ian M.

doi:10.1039/d3cc05369e

Chem. Commun.

2024

DOI: 10.1039/d3cc05369e

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Contrasting reactivity of B–Cl and B–H bonds at [Ni(IMes)₂] to form unsupported Ni-boryls

Gabrielle Audsley,

Ambre Carpentier,

Anne-Frédérique Pécharman

et al.

Abstract: [Ni(IMes)2] reacts with chloroboranes via oxidative addition to form rare unsupported Ni-boryls. In contrast, the oxidative addition of hydridoboranes is not observed and products from competing reaction pathways are identified....

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Contrasting reactivity of B–Cl and B–H bonds at [Ni(IMes)₂] to form unsupported Ni-boryls

Abstract: [Ni(IMes)2] reacts with chloroboranes via oxidative addition to form rare unsupported Ni-boryls. In contrast, the oxidative addition of hydridoboranes is not observed and products from competing reaction pathways are identified....

Cited by 0 publications

References 40 publications

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Contrasting reactivity of B–Cl and B–H bonds at [Ni(IMes)2] to form unsupported Ni-boryls

Abstract: [Ni(IMes)2] reacts with chloroboranes via oxidative addition to form rare unsupported Ni-boryls. In contrast, the oxidative addition of hydridoboranes is not observed and products from competing reaction pathways are identified....

Cited by 0 publications

References 40 publications

No citations

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Contrasting reactivity of B–Cl and B–H bonds at [Ni(IMes)₂] to form unsupported Ni-boryls