2013
DOI: 10.2298/tsci110206083k
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Contribution study of the thermodynamics properties of the ammonia-water mixtures

Abstract: The full thermodynamic study of the absorption refrigeration units requires the knowledge of the thermodynamic properties of the used mixture. The present work deals with the mathematical modeling of the thermodynamic properties of ammonia-water mixtures using various models. The presented model covers high vapor-liquid equilibrium pressures up to 110 [bar] and temperatures from 230 to 600 [K]. Furthermore, the calculation of the thermodynamic properties of the ammonia-water mixtures and their pure comp… Show more

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Cited by 17 publications
(7 citation statements)
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“…It includes in its lower part, isobar and isotherm networks, as well as liquid vapor equilibrium curves in equal concentrations. In the upper part, the reference curves allow to establish the characteristics of the vapor phase, starting from a certain equilibrium point in the lower part (Kherris, S., 2013). To determine the enthalpy, we enter with the concentrations obtained from the mass balance on the "x" axis, we enter with a vertical line up to the pressure at which it is being evaluated and finally with a horizontal line up to the "y" axis where the enthalpy can be read, this can be seen in Figure 3.…”
Section: Journal Of Technological Developmentmentioning
confidence: 99%
“…It includes in its lower part, isobar and isotherm networks, as well as liquid vapor equilibrium curves in equal concentrations. In the upper part, the reference curves allow to establish the characteristics of the vapor phase, starting from a certain equilibrium point in the lower part (Kherris, S., 2013). To determine the enthalpy, we enter with the concentrations obtained from the mass balance on the "x" axis, we enter with a vertical line up to the pressure at which it is being evaluated and finally with a horizontal line up to the "y" axis where the enthalpy can be read, this can be seen in Figure 3.…”
Section: Journal Of Technological Developmentmentioning
confidence: 99%
“…V (with composition y i ) is the vapour product and L (with composition x i ) is the liquid product. The Equations for the enthalpy and the Gibbs free energy equation [28][29][30] are as follows:…”
Section: Governing Equationsmentioning
confidence: 99%
“…The main problem with LiBr-H2O fluids mixture is the crystallization of the system [3], while the NH3-H2O couple can cause corrosion of the installation. Since, the ammonia has been used as refrigerant in absorption cooling systems for a long time [4]; the choice of the binary ammonia-water solution (H2O-NH3) as the working fluid of the refrigeration machine [5][6] refer to this mixture presents very interesting characteristics and advantages [7], in particular when attempting to produce cold at temperatures below zero degree Celsius [8][9]. In other words, improving a machine reverts to improving its performances.…”
Section: Introductionmentioning
confidence: 99%