On the upper reaches of the Ishite River, Japan the stream water is diverted completely at about 3 km above the Ishitegawa Reservoir, except under flood conditions. The chemical composition of the regenerated streamflow 2.4 km downstream from the diversion was determined 70 times during two years (1986-7) to investigate the effects of the diversion on water chemistry. Factor analysis suggested that two main factors controlled the water chemistry. Factor 1 explained 45.7% of the total variance and was correlated positively with the concentrations of Ca2+, Mg2+, Na+, HCO; , SO:and CI-, which seemed to reflect the leaching of dominant ions from the catchment soil. The factor 1 score was correlated negatively with the ecological 'Ca-Mg index' (r2 = 0.912), a low value of which is necessary to avoid phosphorus enrichment by phytoplankton in the downstream reservoir. The diversion seemed to contribute to this purpose because the log flow-rate value was correlated positively with the index (r2 = 0.730). On the other hand, factor 2 explained 10.2% of the total variance and was correlated positively with NO; concentration and negatively with pH. Factor 2 was considered in relation to the partial pressure of dissolved CO, gas in the stream water and appeared to be a complex biological factor that reflected CO, production in the catchment soil and consumption in the stream, KEY WORDS Diverted stream Chemical composition Factor analysis Ca-Mg index 1988). The inflow of river water with a low Ca-Mg index [log(Ca/Mg) -0.5 log(Ca + Mg) using calcium and magnesium concentrations in mmol 1-I; Kagawa and Togashi, 19891 is necessary to avoid abundant phytoplankton growth because a high Ca-Mg index leads to high phytoplanktonic particulate phosphorus concentrations under continuous feeding of river waters low in phosphorus (Kagawa and Togashi, 1989;Kagawa, 1989;1990). This paper seeks to clarify the controlling factors of the chemistry of the diverted part of the Ishite River and the effects of diversion on this ecological water quality index.
MATERIALS AND METHODS
Study area and samplingThe study area is shown in Figure 1. A sampling station, S1, was set up 214 m above sea level on the main stream of the Ishite River, just above the Ishitegawa Reservoir. The symbol S1 relates to earlier investigations 0886 -9375/92/03029 1 -12% 1 1 .OO