The transition dynamics of photons between an optical soliton in a nonlinear dielectric waveguide and a spatially coupled surface-plasmon excitation on a parallel flat metal surface can be formulated in analogy to that of a Josephson junction of two-level (double-well) Bose-Einstein condensates, albeit with a nonlinear coupling that inherently depends on the population imbalance of the levels. The present work demonstrates that asymmetric Rosen-Zener-like transitions can be obtained through this optical Josephson junction, by turning on and off the coupling across a hyperbolically varying separation between the soliton and the surface-plasmon. The transitions can generate full population transfer, population splitting, or merging between the quasistationary initial and final states, which are defined by a fixed population imbalance in the decoupled limit. Transitions from a pure soliton or pure surface-plasmon initial state are found to be robust against the relative phase, whereas the transitions from an initial state with mixed population depend strongly on the relative phase. The soliton-surface-plasmon system also bears similarities to the spatially coupled optical waveguides which are introduced further as the classical analogs of the spatial adiabatic passage and stimulated Raman adiabatic passage mechanisms in quantum and atom optics.