In this work, we report a new chaotic population biology system with one prey and two predators. Our new chaotic population model is derived by introducing two nonlinear interaction terms between the prey and predator-2 to the Samardzija-Greller population biology system (1988). We show that the new chaotic population biology system has a greater value of Maximal Lyapunov Exponent (MLE) than the Maximal Lyapunov Exponent (MLE) of the Samardzija-Greller population biology system (1988). We carry out a detailed bifurcation analysis of the new chaotic population biology system with one prey and two predators. We also show that the new chaotic population biology model exhibits multistability with coexisting chaotic attractors. Next, we use the integral sliding mode control (ISMC) for the complete synchronization of the new chaotic population biology system with itself, taken as the master and slave chaotic population biology systems. Finally, for practical use of the new chaotic population biology system, we design an electronic circuit design using Multisim (Version 14.0).