The dynamics of drop‐on‐demand (DoD) droplet formation and subsequently impact on the solid substrate are investigated using a three‐dimensional (3‐D) multirelaxation‐time (MRT) pseudopotential lattice Boltzmann (LB) model. The wettability of nonideal nozzle plate and solid substrate is modeled by a geometric scheme within the LB framework. The dynamics of droplet formation are explored in a range of the inverse of Ohnesorge number
Z=4.95,
11.57, and
28.17, and the Reynolds number
Re=39.6,
58.9, and
136.4. For
Z=4.95, no satellite droplet is observed and the wettability of nozzle plate greatly influences the velocity and length of jetting fluids. For
Z=11.57, the filament breakup and recombination are observed. The moment of filament breakup is delayed with advancing contact angle
θA increasing. For
Z=28.17 with
Re=136.4, the primary and satellite droplets could not be recombined with
θA=30° and
θA=60° which agree with the literature. Whereas with
θA=90°, the recombination occurs. The dynamics of subsequent oscillating droplet impact on the substrate are similar to that of equilibrium droplet which could obtain high‐resolution printed features. Consequently, considering
θA=90° with large
Z and
Re numbers, the printable range could be extended which could help increase the printing frequency and boost the production outputs of inkjet printing. © 2018 American Institute of Chemical Engineers AIChE J, 64: 2837–2850, 2018