“…Up to now, MnO 2 with diverse structures and morphologies (such as nanosheets [4], hollow nanospheres [5], nanoflowers [6], nanowires/nanorods [7,8], thin films [9], and nanotubes [10]) and different crystalline phases (such as a [11], b [12], g [13], and d [14]) have been fabricated via electrochemical and chemical routes, and their electrochemical properties have been investigated. These studies indicate that the outstanding nanostructures and crystalline phases of the MnO 2 materials have been regarded as critical factors to influence their properties.…”