The characteristics of a MOS diode with Mg-ion-implanted GaN before activation annealing were investigated. Mg ion implantation onto n-GaN with slightly high Si doping concentration (5×10 17 cm -3 ) was performed with a moderate dosage (1.5×10 12 cm -2 ). The completed MOS diode showed n-type features. The capacitance-voltage (C-V) and capacitance-frequency (C-f) characteristics of the MOS diode indicated that shallow surface Fermi level pinning and deep depletion occurred simultaneously. By applying the conductance method to the measured C-f characteristics, a discrete level at 0.2-0.3 eV below the conduction band edge was detected. On the basis of the simulation of the high-frequency-limit C-V curve, the detected discrete level distributed in the bulk of n-GaN rather than at the insulator/semiconductor interface, so that it caused surface Fermi level pinning at a relatively shallow energy level and deep depletion owing to its acceptorlike nature simultaneously.