Control of Silver(I)–Dialkyl Chalcogenide Coordination by a Synthetic Cavity

Kohyama, Yuh; Murase, Takashi; Fujita, Makoto

doi:10.1002/ange.201406224

Cited by 11 publications

(1 citation statement)

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“…[14][15][16][17][18] The main approach is to utilize metal-organic compounds with restricted shapes and sizes to control the chemo-, regio-, and stereoselectivity of a certain transformation. [19][20][21][22][23][24] Some of the metal-organic compounds involve homoleptic metallic unit centers featuring specific coordination geometry. Carbon sequestration is a process through which atmospheric freely available carbon dioxide (CO2) is captured and stored through a natural process, so it has become a most important feature in environmental protection.…”

Section: Introductionmentioning

confidence: 99%

Multicomponent Self-assembly of a Multinuclear Heterometal–Organic Polymer for CO2 Reduction

Qiao

2023

AETR

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To address the greenhouse effect, scientists have never stopped exploring efficient photocatalytic CO2 reduction systems, and metal-organic compounds have recently emerged as a solution for overcoming global warming and climate issues. Under the irradiation of visible light, the catalytic activity, stability, and selectivity of most of the non-noble metal complexes reported so far are unsatisfactory. To efficiently fix CO2, Ru multinuclear heterometal–organic compound was obtained for carbon dioxide reduction. The as-synthesized M-Zn complex (M =Ru) catalysts exhibit special catalytic activity for the reduction of CO2 because of the immobilized metal ions serving as active sites during the reaction. This study proposes a general strategy for CO2 reduction through high levels in metal-organic polymers to achieve effective environmental protection and governance.

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Section: Introductionmentioning

confidence: 99%

Multicomponent Self-assembly of a Multinuclear Heterometal–Organic Polymer for CO2 Reduction

Qiao

2023

AETR

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Direct X‐Ray Scattering Evidence for Metal–Metal Interactions in Solution at the Molecular Level

et al. 2015

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The study of the aggregation of small molecules in solution induced by metallophilic interactions has been traditionally performed by spectroscopic methods through identification of chemical changes in the system. Herein we demonstrate the use of SAXS (small‐angle X‐ray scattering) to identify structures in solution, taking advantage of the excellent scattering intensity of heavy metals which have undergone association by metallophilic interactions. An analysis of the close relationship between solid‐state and solution arrangements of a dynamic [Ag2(bisNHC)2]2+ (NHC=N‐heterocyclic carbene) system, and how they are complementary to each other, is reported.

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Regio‐ and Enantioselective Photodimerization within the Confined Space of a Homochiral Ruthenium/Palladium Heterometallic Coordination Cage

Guo

et al. 2017

Angewandte Chemie

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Control of Silver(I)–Dialkyl Chalcogenide Coordination by a Synthetic Cavity

Abstract: The discrete cavity of a self-assembled palladiumtris(4-pyridyl)triazine cage dictates the ratio of metal, ligand, and a non-coordinative molecule in the formation of silver(I)dialkyl chalcogenide (Et, nBu; S, Se) complexes and defines their coordination arrangement.

Cited by 11 publications

References 50 publications

Multicomponent Self-assembly of a Multinuclear Heterometal–Organic Polymer for CO2 Reduction

Multicomponent Self-assembly of a Multinuclear Heterometal–Organic Polymer for CO2 Reduction

Direct X‐Ray Scattering Evidence for Metal–Metal Interactions in Solution at the Molecular Level

Regio‐ and Enantioselective Photodimerization within the Confined Space of a Homochiral Ruthenium/Palladium Heterometallic Coordination Cage

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