Control of texture in alumina by colloidal processing in a strong magnetic field

Abstract

Electrical, mechanical and other properties of ceramic materials can be controlled by designing their microstructures. It had generally been difficult to utilize a magnetic field for tailoring the microstructure in feeble magnetic ceramics, such as Al 2 O 3 ; however, the possibility of controlling the microstructure by a magnetic field occurred with the development of superconducting magnets. In this review paper, we introduce a novel processing for the microstructual design in ceramics by colloidal processing in a strong magnetic field and an electric field. We demonstrate that the textured alumina can be fabricated by slip casting in a strong magnetic field and the production of alumina/alumina laminar composites with different crystalline-oriented layers can be achieved by electrophoretic deposition in a strong magnetic field. In order to control the texture using a magnetic field, a good dispersion of powder in a suspension is necessary because a strong attractive force between the agglomerated particles prevents each particle in a suspension from rotating in the magnetic field. The degree of orientation depends on the processing factors, such as heating temperature, viscosity of suspension, etc. And the grain growth in Al 2 O 3 matrix enhances crystallographic texture development. The bending strength of the laminar composite depended on the direction of the multilayered microstructure with alternate crystalline-oriented layers. Crack propagation and fracture mode depend on the direction of microstructure in the laminar composite with controlled crystalline orientation. q

Numerical simulation of chainlike cluster movement of feeble magnetic particles by induced magnetic dipole moment under high magnetic fields

“…For example, needle-like fiber [1,2], carbon nanotubes [3,4] and inorganic crystals [5][6][7], which are typical one-dimensional materials, have attracted much interest because of their unique properties and potential applications in mechanical, electrical and thermodynamic devices. Chainlike materials are also considered one dimensional.…”

Porous ceramics mimicking nature—preparation and properties of microstructures with unidirectionally oriented pores

“…Many recent studies attempted to control the microstructure in ceramics using magnetic fields [76]. Miyagawa and Shinohara [77] prepared unidirectional porous Al 2 O 3 ceramics from an Al 2 O 3 slurry containing Ni wires cast in a plaster mold.…”

Nano Ceramics Center, National Institute for Materials Science

“…By changing the direction of the substrate relative to that of the magnetic field, we succeeded in fabricating oriented laminated ceramics [8], as shown in Fig. 8.…”