High-ion-temperature ͑exceeding 5 keV͒ hydrogen plasmas have been successfully produced in the Large Helical Device ͓Iiyoshi et al., Nucl. Fusion 39, 1245 ͑1999͒; Motojima et al., Nucl. Fusion 47, S668 ͑2007͔͒ with the ion heat confinement improvement in the core region. The experimental ion heat diffusivity at the core region is found to be almost independent of the ion temperature, T i ͑even decreasing as T i increases͒. The neoclassical ͑NC͒ ripple transport is suppressed by the ambipolar radial electric field, E r ͑Ͻ0͒ predicted by NC transport fluxes. The temperature ratio, T i / T e , is one of the key parameters to reduce the NC ambipolar particle and heat fluxes. Thus, it is suggested that the selective ion heating ͑making T i / T e larger͒ is a plausible approach to further increase T i . Spontaneous rotation is evaluated in these high-T i plasmas, in which a co-directed component is recognized at the radial location with a large T i gradient, in addition to the tokamak-like counter-directed component expected for E r Ͻ 0.