This study showed that the trihalomethane (THM) concentration in finished water that had ken treated at 35.6" F (2°C) was significantly lower than in water treated at 71.6" F (22°C). Water temperature did not appear to affect the removal of total organic carbon (TOC) during coagulation with metal ion salts, but color removal was slightly reduced at low temperatures. The efficiency of coagulation for removing TOC, color, and THM formation potential improved when the water was treated at pH 5 rather than pH 7, regardless of temperature. Removal of low-molecular-weight organic substances was found to be more difficult at 35.6" F (2°C) than at 71.6" F (22°C). The data obtained suggest that reduced THM concentrations in finished water during winter are strictly a function of the reduced rate of THM formation.Campet alaconcluded that although low temperature did not affect the flocculation step of treatment, settling efficiency was impaired. Morris and Knocke6 presented quantitative results showing that low temperatures reduced the efficiency of metal ion coagulants for removal of turbidity from surface waters. They concluded that low temoeratures at times During the past ten years, considerable research has been conducted to determine how the disinfection of drinking water with chlorine can lead to the formation of potentially carcinogenic compounds, particularly trihalomethanes (THMs). Studies have also been conducted to evaluate methods of removing THMs from water with treatment methods such as air stripping' :' and adsorption by activated carbon columns." -" In addition, significant research has focused on methods of removing the organic precursors of THMsmethods such as the optimization of coagulation-flocculation systems.promoted the formation of extremely ciency and poor coagulation. Earlier work small particles, which did not settle mentioned possible problems with tur-well. Thus, their results showed that bidity removal when alum coagulation temperature affected both the flocculawas used at low temperatures, although tion and settling phases of treatment. little quantitative data were presented.7With the current need to control the One major operational difficulty that water treatment plants face in attempting to meet the THM standards is related toseasonal fluctuations in water quality. For example, changes in water temperature appear to affect the kinetics and equilibrium of metal hydroxide precipitation, resulting in a potentially adverse effect on coagulation systems.6 The flocculation and sedimentation stages of water treatment can also be affected by water temperature as a result of changes in solution viscosity and density. Until recently, temperature variations were not recognized as one of the potential causes of water treatment plant ineffi-APRIL 1986 Figure 1. Effect of incubation temperature on the rate of THM formation in Harwood' s Mill Reservoir water treated with 60 mg alum/L at pH 7 Figure 2. Effect of alum dose and temperature on turbidity removal from Chickahominy River water by coagulation ...