2011
DOI: 10.1021/am2010288
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Controllable Growth of Highly Ordered ZnO Nanorod Arrays via Inverted Self-Assembled Monolayer Template

Abstract: This article presents a facile and effective approach to the controllable growth of highly ordered and vertically aligned ZnO nanorod arrays on the GaN substrate via a hydrothermal route by using the TiO(2) ring template deriving from the polystyrene microsphere self-assembled monolayer. The size of TiO(2) ring template can be flexibly tuned from 50 to 400 nm for the 500 nm polystyrene microspheres by varying the time of reactive ion etching and the concentration of TiO(2) sol. As a result, the diameter of the… Show more

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Cited by 45 publications
(43 citation statements)
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“…Although the ZnO (002) peak dominated, weak ZnO (101), (102), and (103) peaks were observed clearly in the XRD pattern of sample 3, implying the poor c -axis orientation of ZnO nanostructures grown on dip-coated seed layer. From the XRD pattern of sample 1, we can see that ZnO (100), (002), (102), (110), and (103) peaks appear at about the same intensity, demonstrating the random orientation of ZnO nanostructures grown on the bare Si substrate [14,21]. Conclusions drawn from the XRD patterns are in high accordance with those drawn from earlier SEM results.…”
Section: Resultssupporting
confidence: 85%
“…Although the ZnO (002) peak dominated, weak ZnO (101), (102), and (103) peaks were observed clearly in the XRD pattern of sample 3, implying the poor c -axis orientation of ZnO nanostructures grown on dip-coated seed layer. From the XRD pattern of sample 1, we can see that ZnO (100), (002), (102), (110), and (103) peaks appear at about the same intensity, demonstrating the random orientation of ZnO nanostructures grown on the bare Si substrate [14,21]. Conclusions drawn from the XRD patterns are in high accordance with those drawn from earlier SEM results.…”
Section: Resultssupporting
confidence: 85%
“…fabrication method named as nanosphere lithography for the production of periodic particle array surfaces with nanometer-scale features. NSL was firstly reported by the research work of Hulteen and Van Duyne [17] and has been widely employed in the area of two-and three-dimensional (2D and 3D) micro/nanostructures patterning, such as quantum dots, nanowires, nanomesh, antireflection structure (ARS), and 3D inverse-opal photonic crystals [18][19][20][21][22][23]. Compared to those traditional sophisticated lithographic methods, NSL has shown a great many advantages that include a simple nanofabrication technique, an inexpensive route for the patterning of long-range periodic nanostructure arrays in a large scale area, and high throughput.…”
Section: Introductionmentioning
confidence: 99%
“…25 26 38 This AR-HSM aided approach can be readily extended to other functional substrates by simply adding a functional material deposition process before spincoating. 4 30 39 These functional materials may be conductive metal, and special seed etc. The conductive metal can give rise to localized surface plasmon resonance (LSPR) and be applied in detecting and sensing.…”
Section: Controllable Fabricationmentioning
confidence: 99%
“…In the past decade, much progress has been made in the study of nanostructure arrays for their numerous applications in bio-chemical sensors, 1-3 photovoltaic devices, [4][5][6] surface-enhanced Raman scattering (SERS) substrates, [7][8][9][10] and etc. All of these applications are based on the electron-photon coupling interaction between the nanostructure arrays and incidence light.…”
Section: Introductionmentioning
confidence: 99%