We extend the concepts of the Autler-Townes doublet and triplet spectroscopy to quartuplet, quintuplet and suggest linkages in sodium atom in which to display these spectra. We explore the involved fundamental processes of quantum interference of the corresponding spectroscopy by examining the Laplace transform of the corresponding state-vector subjected to steady coherent illumination in the rotating wave approximation and Weisskopf-Wigner treatment of spontaneous emission as a simplest probability loss. In the quartuplet, four fields interact appropriately and resonantly with the five-level atom. The spectral profile of the single decaying level, upon interaction with three other levels, splits into four destructively interfering dressed states generating three dark lines in the spectrum. These dark lines divide the spectrum into four spectral components (bright lines) whose widths are effectively controlled by the relative strength of the laser fields and the relative width of the single decaying level. We also extend the idea to the higher-ordered multiplet spectroscopy by increasing the number of energy levels of the atomic system, the number of laser fields to couple with the required states. The apparent disadvantage of these schemes is the successive increase in the number of laser fields required for the strongly interactive atomic states in the complex atomic systems. However, these complexities are naturally inherited and are the beauties of these atomic systems. They provide the foundations for the basic mechanisms of the quantum interference involved in the higher-ordered multiplet spectroscopy.