“…UHTCs typically consist of refractory ceramics, primarily carbides, borides, and oxides, owing to their high melting temperature, chemical resistance, and mechanical properties 3,5,7 . Group IV–V transition metal carbides and borides, such as HfC, ZrC, TaC, TiC, HfB 2 , ZrB 2 , and TiB 2 , offer the highest melting temperatures (ranging from ∼3100°C to ∼3900°C), making them potential materials of choice for cutting tools, thermal protection, and high‐temperature tribological and nuclear power applications 8–15 . However, due to their extremely high melting temperatures, sintering of pure transition metal carbide and boride ceramics is challenging as these materials display strong covalent bonds and low self‐diffusion coefficients, both of which hinder densification 5,9 .…”