Lignin is a promising feedstock for renewable fuels and chemicals
due to its aromatic skeleton and natural abundance. Lignin can be
converted to diverse aromatic monomers as well as dicarboxylic acids
depending on the applied conversion technologies. Despite its great
potential, its native and processing-induced heterogeneity and complexity
limit the conversion efficiency and product selectivity. In this study,
magnesium ferrite (MgFe2O4) nanoparticle–peracetic
acid (PAA) has been investigated as an efficient catalyst–oxidant
incorporation for catalytic oxidative depolymerization of lignin under
mild conditions. Typically, the increase in processing severity can
enhance the lignin conversion while it results in the further decomposition
of aromatic compounds to dicarboxylic acids. However, in this study,
the incorporation of MgFe2O4 nanoparticles and
PAA not only enhanced the total product yield but also improved the
selectivity of aromatic monomers. The oxidative depolymerization system
using the catalyst–oxidant combination resulted in 46 wt %
of total oil product with a 61% selectivity of aromatic monomers under
mild temperature (90 °C). In addition, this combination catalyst
showed relatively good cycling stability based on the total product
yield after recycling five times via magnetic separation. Overall,
MgFe2O4 nanoparticles play an important role
as a co-catalyst with a PAA oxidant in the oxidative conversion of
lignin with an enhanced conversion efficiency and recyclability, and
it will facilitate the valorization of lignin in future bio-based
fuels and chemicals.