Controlling the size and shape of Mg-MOF-74 crystals to optimise film synthesis on alumina substrates

Abstract

Mg-MOF-74 is a metal organic framework with the highest

CO2 Adsorption in Metal-Organic Framework Mg-MOF-74: Effects of Inter-Crystalline Space

“…This is consistent with our results reported here. In a recent work, Campbell and Tokay [ 41 ] have also shown that the crystal size of Mg-MOF-74 can be controlled by varying the fraction of ethanol and water in the reaction solution relative to dimethyl formamide. By varying this composition, they obtained smaller crystallites with sizes varying between 8 nm to 50 nm.…”

From metal–organic framework to morphology- and size-controlled 3D mesoporous Cr2O3 toward a high surface area and enhanced volatile organic compound oxidation catalyst

“…What's more, in addition to the good shape control, the size of 3D mesoporous Cr 2 O 3 can also be regulated by controlling the synthesis conditions of their MOF templates. [26][27][28][29][30] For example, ca. 800 nm octahedral mesoporous Cr 2 O 3 were fabricated from ca.…”

Mass transport through metal organic framework membranes

“…. Mg-MOF-74 presented highest CO 2 adsorption capcacity due to the open Mg sites (Fig. 10a) [132]. Therefore, the Mg-MOF-74 provided high hinderance on the CO 2 diffusion caused by the interaction between open Mg sites and CO 2 .…”