Controlling the steepness of gate-opening behavior on elastic layer-structured metal–organic framework-11 via solvent-mediated phase transformation
Shotaro Hiraide,
Keisuke Nishimoto,
Satoshi Watanabe
Abstract:The phase of the precursor of ELM-11 affects the steepness of its gate-opening behavior, and this phase can be controlled by solvent-mediated phase transformation.
Flexible metal–organic frameworks (MOFs) show S-shaped adsorption isotherms due to their structural transition. This behavior changes depending on their particle size. This paper elucidates the size effect using a multi-scale simulation model.
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