Water samples were collected from two mountain rivers of contrasting climates, viz., humid, Muthirapuzha River Basin (MRB) and semi-arid, Pambar River Basin (PRB) during monsoon (MON), post-monsoon (POM) and pre-monsoon (PRM) seasons, and were analyzed to understand the spatio-temporal variability as well as the sources and processes controlling hydrogeochemistry. In MRB and PRB, Ca 2+ and Mg 2+ dominate the cations, while Cl − dominates the anions in MRB and HCO 3 − dominates the anions in PRB. PRB shows an elevated level of ionic abundance and higher degree of mineralization, due to multiple factors such as semiaridity, discharge dominated by groundwater, lithological variations and the influences of carbonates and soil evaporites. However, K + , Cl − and H 4 SiO 4 are relatively higher in MRB, implying significance of both anthropogenic activities and intense silicate weathering. The Ca 2+ + Mg 2+ /HCO 3 − ratios in MRB are also relatively larger than PRB, suggesting high intensity of anthropogenic influences in MRB. Downstream variation of hydrogeochemistry implies a general decreasing trend in MRB, which is attributed to dilution due to high discharge, whereas hydrogeochemistry of PRB shows an increasing downstream trend, by which, the significance of semi-arid climate of the downstream tracts of the basin is implied. Both MRB and PRB show temporal variability in hydrogeochemical attributes implying the role of monsoon rainfall determining stream water composition. − (with respect to Na + ) indicates multiple sources for Cl − (i.e., anthropogenic as well as atmospheric). Even though there are significant differences in water types between MRB and PRB, most of the waters of both the basins are considered to be "transitional". Relatively higher pCO 2 in stream waters (compared to atmosphere) is observed and the phenomenon is attributed to the influent nature of the stream discharge (i.e., contributed by groundwater which is significantly enriched in CO 2 ) and the slower rate of re-equilibration (i.e., solubility vs. release of CO 2 ) with atmosphere. Hence, evidently the hydrogeochemical composition of MRB and PRB is jointly controlled by weathering of silicate and carbonate minerals as well as anthropogenic activities and is influenced by climatic seasonality. The spatiotemporal variability of hydrogeochemical attributes of MRB and PRB is mainly due to the variations in climate, lithology, hydrologic pathways and degree of various anthropogenic activities.