Convenient preparation and structures of selenometalates MoSe42-, WSe42- and MoSe92- from polyselenide anions and metal carbonyls

Syntheses, Structures and Optical Nonlinearities of Heteroselenometallic W–Se–Cu Cluster Compounds Containing Bridging Phosphane Ligands

“…[Et 4 N] 2 [WSe 4 ] [43] and [Cu 3 (µ 3 -I) 2 (µ-dppm) 3 ]I [24] (1a) were prepared according to literature methods. [Cu(MeCN) 4 ]- [PF 6 ] was synthesized by the reaction of Cu 2 O powder with HPF 6 in acetonitrile.…”

Iridium(III) and rhodium(III) cyclometalated complexes containing sulfur and selenium donor ligands

“…The atom labeling scheme for Buppy À is shown below [M(Buppy) 2 Cl] 2 (M ¼ Ir (1), Rh (2)) were synthesized by reactions of BuppyH with IrCl 3 and RhCl 3 , respectively, in alcohols as described elsewhere [25]. K[N(Ph 2 PQ) 2 ] (Q ¼ S [26] or Se [27]) and [Et 4 N] 2 [WQ 4 ] (Q ¼ S [28] or Se [29]) were synthesized according to literature methods. Other reagents were obtained from commercial sources and used as received.…”

“…for C 54 H 52 N 3 P 2 Se 2 Ir: C, 55. 29;H,4.64;N,3.59. Found: C,55.79;H,4.75;N,3.43% (10), Rh (11)) To a solution of 1 (40 mg, 0.031 mmol) in MeOH (20 ml) was added Ag(OTf) (OTf ¼ triflate, 0.062 mmol) and the mixture was stirred at room temperature for 1 h and filtered.…”

Reaction of transition metal carbonyls with soluble polyselenides: synthesis and structure of [(C6H5)4P]2[Re2(Se4)2(CO)6]

“…Analytical data were provided by Atlantic Microlabs. The polyselenide salt K2Se3, used as starting material, was prepared as previously described (6). All other reagents and solvents are commercially available and were used as received.…”

“…We have recently reported the reactions of soluble polysulfides and polyselenides with group 6 metal hexacarbonyls under anhydrous condition, to form binary metal chalcogenide anions via an oxidative decarbonylation reaction (6). This is in contrast to the reactions with polytellurides, which form coordinated polytelluride ring complexes (7).…”