In this paper, we present several new a posteriori error estimators and two adaptive mixed finite element methods AMFEM1 and AMFEM2 for the Hodge Laplacian problem in finite element exterior calculus. We prove that AMFEM1 and AMFEM2 are both convergent starting from any initial coarse mesh. In addition, we prove the quasi-optimality of AMFEM2. Comparing to existing literature, our results work on Lipschitz domains with nontrivial cohomology and provide the first norm convergence and quasi-optimality results for the Hodge Laplacian. Key words. a posteriori error estimate, adaptive mixed finite element method, finite element exterior calculus, Hodge Laplacian, convergence, optimality AMS subject classifications. 65N12, 65N15, 65N30, 65N50, 41A25 ∇ − → H(curl, Ω) curl −−→ H(div, Ω) div − − → L 2 (Ω).