Conversion of a manganese-carbon-bonded complex to a manganese-oxygen-bonded complex, some reactions of manganese carbonato complexes

The manganese carbonyl complex [MnBr(CO)3L] (1), where L = Ph2POCH2CH2OPPh2, was prepared by reacting [MnBr(CO)5] with the bidentate ligand 1, 2‐Bis(diphenylphosphinite)ethane. From this compound and the appropriate phosphite, phosphinite or phosphonite ligands were synthesized the complexes [MnBr(CO)2LL′], where L′ = P(OMe)3 (2) or P(OEt)3 (3) and [MnBr(CO)3L′2], where L′ =PPh(OEt)2 (4) or PPh2(OEt) (5).The obtained compounds have been characterized by elemental analysis, mass spectrometry, IR and NMR (1H, 13C and 31P) spectroscopies and X‐ray diffractometry for the complexes 1, 4 and 5.

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Synthesis, Structure and Reactivity of [1, 2‐Bis(diphenylphosphinite)ethane]bromotricarbonylmanganese(I) with Reactions of Phosphites, Phosphonites. and Phosphinites

Bravo

Castro

García‐Fontán

et al. 2003

Zeitschrift anorg allge chemie

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The preparation and crystal structures of some tricarbonylmanganese(I) octahedral complexes containing the 1,1-dimethylamino-2,2-diphenylphosphinoethane ligand

2004

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The preparation and crystal structures of a covalent tetrafluoroborato complex, (CO)3(dppfe)MnFBF3, and of a related ionic complex, [(CO)4(dppfe)Mn]BF4 [(dppfe) = bis-(1,1′-diphenylphosphino)ferrocene]

2005

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Conversion of a manganese-carbon-bonded complex to a manganese-oxygen-bonded complex, some reactions of manganese carbonato complexes

Cited by 8 publications

References 17 publications

Synthesis, Structure and Reactivity of [1, 2‐Bis(diphenylphosphinite)ethane]bromotricarbonylmanganese(I) with Reactions of Phosphites, Phosphonites. and Phosphinites

Synthesis, Structure and Reactivity of [1, 2‐Bis(diphenylphosphinite)ethane]bromotricarbonylmanganese(I) with Reactions of Phosphites, Phosphonites. and Phosphinites

The preparation and crystal structures of some tricarbonylmanganese(I) octahedral complexes containing the 1,1-dimethylamino-2,2-diphenylphosphinoethane ligand

The preparation and crystal structures of a covalent tetrafluoroborato complex, (CO)3(dppfe)MnFBF3, and of a related ionic complex, [(CO)4(dppfe)Mn]BF4 [(dppfe) = bis-(1,1′-diphenylphosphino)ferrocene]

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