Conversion of rice straw into 5-hydroxymethylfurfural: review and comparative process evaluation

Wanninayake, Poornima; Rathnayake, Mahinsasa; Thushara, Dilantha; Gunawardena, Sanja

doi:10.1007/s13399-021-01351-x

Cited by 20 publications

(33 citation statements)

References 267 publications

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“…FF and HMF were determined as the kind of cheap furan derivatives that can be obtained directly from biomass on a large scale. [88][89][90][91][92][93][94] For example, FF (96% yield) can be obtained from corn stalk, 95 and HMF (99% yield) can be obtained by using fructose as a reactant. 96 There is no doubt that FF and HMF are very attractive raw materials for the production of renewable aromatic hydrocarbons through the DA/ aromatization strategy.…”

Section: Da Reaction Strategy For Ff and Hmfmentioning

confidence: 99%

Advances in Diels–Alder/aromatization of biomass furan derivatives towards renewable aromatic hydrocarbons

Jiang

et al. 2022

Catal. Sci. Technol.

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Section: Da Reaction Strategy For Ff and Hmfmentioning

confidence: 99%

Advances in Diels–Alder/aromatization of biomass furan derivatives towards renewable aromatic hydrocarbons

Jiang

et al. 2022

Catal. Sci. Technol.

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“…Solvent not only serves as a medium, but it also serves as a multi‐functional platform as it dissolves the substrates and acts as a catalyst to enhance reaction kinetics and stabilize the reactants, intermediates, and HMF for a higher HMF yield and minimize the unwanted side reactions 32 . Water, organic solvents (such as polar aprotic and biomass‐derived solvents), ionic liquids, and deep eutectic solvents are some of the frequent solvents used in the study of HMF synthesis 32 …”

Section: Reaction System For Synthesis Of Hmfmentioning

confidence: 99%

“…The MIBK could accelerate the breakdown of glucose by extracting the HMF from the aqueous phase and minimizing the formation of by‐products to obtain a higher yield of HMF 67 . However, the application of MIBK for large‐scale HMF production was impeded due to the expensive solvent cost and there is a possibility for the MIBK and HMF to undergo side reaction of acid‐catalyzed condensation and produce aldolic products 32 …”

Section: Reaction System For Synthesis Of Hmfmentioning

confidence: 99%

Recent reaction systems for the synthesis of 5‐hydroxymethylfurfural (HMF) from carbohydrates with process development analysis: A review

Rani

Karim

Kamarudin

2022

Intl J of Energy Research

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Summary 5‐Hydroxymethylfurfural (HMF) is a versatile biomass‐derived chemical from multifunctional compound. It is also a promising intermediate compound used in various chemical and fuel applications, including pharmaceuticals, solvents, biofuel, and other intermediates. The demand for innovative approaches to renewable energy resources has risen to diminish the dependency on petroleum‐based products and to seek economical and environmentally friendly processes for supplying energy to the world. Fructose, glucose, cellulose, and lignocellulosic materials are the most common feedstocks used to synthesize HMF. This study reviews previous studies on the development of high yield and selectivity of HMF from technical and economic perspectives. The article highlights a few significant parameters and focused on the solvent system used for the synthesis of HMF in the lab scale and through the development of process modeling using simulation software such as Aspen Plus to perform the techno‐economic analysis (TEA), which analyses the economic feasibility of the developed production process. The TEA can estimate the capital investment needed, including feedstock, catalyst, and equipment cost, and the final product's minimum selling price (MSP). HMF is cost‐efficient due to higher operational costs from the higher cost of fructose feedstock. By studying this analysis, the overall cost of HMF production can be minimized and more economically competitive with current commercial production. Besides, to make the production of HMF more cost‐effective, more research into alternative lignocellulosic feedstocks and the development of novel catalytic systems is needed.

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“…Cellulose, hemicellulose, and lignin are the major components of biomass. , With acidic pretreatment under mild hydrothermal conditions, biomass with a polymeric structure will be converted into small molecules such as monosaccharides or disaccharides. Among the three platform compounds mentioned above, HMF and LA come from conversion of cellulose, while FF is mainly transformed from hemicellulose …”

Section: Introductionmentioning

confidence: 99%

“…Among the three platform compounds mentioned above, HMF and LA come from conversion of cellulose, while FF is mainly transformed from hemicellulose. 6 The Brønsted acid catalyzed hydrolysis is a typical pretreatment of biomass. According to Kennedy and Pons, 7 there are three steps in the typical process of cellulose hydrolysis.…”

Section: Introductionmentioning

confidence: 99%

Critical Review on the Preparation of Platform Compounds from Biomass or Saccharides via Hydrothermal Conversion over Carbon-Based Solid Acid Catalysts

et al. 2021

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The use of carbon-based catalysts to catalyze the hydrothermal conversion of biomass and its derived carbohydrates to produce platform compounds such as 5-(hydroxymethyl)furfural (HMF), levulinic acid (LA), and furfural (FF) has a long history. The excellent thermal stability and chemical activity and low preparation cost of carbon-based catalysts make them develop rapidly in catalytic hydrothermal conversion, which is the core attention in the review. Carbon catalysts are divided into sulfuric acid-based carbon catalysts, phosphoric acid-based carbon catalysts, metal-supported carbon catalysts and other types of carbon catalysts, to study their application to hydrothermal decomposition of monosaccharides, disaccharides, polysaccharides, and biomass. The characteristics of different types of carbon catalysts were introduced. The diversified development of carbon-based catalysts and the upgrading of feedstocks have promoted the improvement of product selectivity, cost, and energy optimization, realizing the transformation of hydrothermal decomposition of biomass into a greener process. However, the development of efficient catalytic systems for hydrothermal conversion of abundant, cheap, and readily available biomass sources is still an ideal choice to expand the process strategy.

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Conversion of rice straw into 5-hydroxymethylfurfural: review and comparative process evaluation

Cited by 20 publications

References 267 publications

Advances in Diels–Alder/aromatization of biomass furan derivatives towards renewable aromatic hydrocarbons

Advances in Diels–Alder/aromatization of biomass furan derivatives towards renewable aromatic hydrocarbons

Recent reaction systems for the synthesis of 5‐hydroxymethylfurfural (HMF) from carbohydrates with process development analysis: A review

Critical Review on the Preparation of Platform Compounds from Biomass or Saccharides via Hydrothermal Conversion over Carbon-Based Solid Acid Catalysts

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