Pedestrian reidentification is a key technology in large-scale distributed camera systems. It can quickly and efficiently detect and track target people in large-scale distributed surveillance networks. The existing traditional pedestrian reidentification methods have problems such as low recognition accuracy, low calculation efficiency, and weak adaptive ability. Pedestrian reidentification algorithms based on deep learning have been widely used in the field of pedestrian reidentification due to their strong adaptive ability and high recognition accuracy. However, the pedestrian recognition method based on deep learning has the following problems: first, during the learning process of the deep learning model, the initial value of the convolution kernel is usually randomly assigned, which makes the model learning process easily fall into a local optimum. The second is that the model parameter learning method based on the gradient descent method exhibits gradient dispersion. The third is that the information transfer of pedestrian reidentification sequence images is not considered. In view of these issues, this paper first examines the feature map matrix from the original image through a deconvolution neural network, uses it as a convolution kernel, and then performs layer-by-layer convolution and pooling operations. Then, the second derivative information of the error function is directly obtained without calculating the Hessian matrix, and the momentum coefficient is used to improve the convergence of the backpropagation, thereby suppressing the gradient dispersion phenomenon. At the same time, to solve the problem of information transfer of pedestrian reidentification sequence images, this paper proposes a memory network model based on a multilayer attention mechanism, which uses the network to effectively store image visual information and pedestrian behavior information, respectively. It can solve the problem of information transmission. Based on the above ideas, this paper proposes a pedestrian reidentification algorithm based on deconvolution network feature extraction-multilayer attention mechanism convolutional neural network. Experiments are performed on the related data sets using this algorithm and other major popular human reidentification algorithms. The results show that the pedestrian reidentification method proposed in this paper not only has strong adaptive ability but also has significantly improved average recognition accuracy and rank-1 matching rate compared with other mainstream methods.