Coordination compounds of polyoxovanadates with a hexametalate core. Chemical and structural characterization of [VV6O13[(OCH2)3CR]2]2-, [VV6O11(OH)2[(OCH2)3CR]2], [VIV4VV2O9(OH)4[(OCH2)3CR]2]2-, and [VIV6O7(OH)6](OCH2)3CR]2]2-

Chen, Qin; Goshorn, D. P.; Scholes, Charles P.; Tan, Xiao Ling; Zubieta, Jon

doi:10.1021/ja00038a033

Cited by 191 publications

(185 citation statements)

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“…Adapted from [260]. 6 and tris = polyalkoxide ligand from tris(hydroxymethyl)alkane) has been investigated [261]. Relevant data are summarized in Scheme 20.…”

Section: Polyoxovanadates and Other Vanadium-containing Polyoxometalamentioning

confidence: 99%

A journey into the electrochemistry of vanadium compounds

Galloni

Conte

2015

Coordination Chemistry Reviews

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“…Adapted from [260]. 6 and tris = polyalkoxide ligand from tris(hydroxymethyl)alkane) has been investigated [261]. Relevant data are summarized in Scheme 20.…”

Section: Polyoxovanadates and Other Vanadium-containing Polyoxometalamentioning

confidence: 99%

A journey into the electrochemistry of vanadium compounds

Galloni

Conte

2015

Coordination Chemistry Reviews

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“…This serves to diminish the charge, and a reducing state of V IV is preferred by the introduction of alkoxide ligands [83]. The substitution of all bridging oxygens with CH 3 O - [84,85] [98].…”

Section: Alkoxohexavanadatesmentioning

confidence: 99%

Hetero and lacunary polyoxovanadate chemistry: Synthesis, reactivity and structural aspects

Hayashi

2011

Coordination Chemistry Reviews

214

126

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Many synthetic methods for heteropolyoxovanadates and lacunary polyoxovanadates have been developed in recent years. We outline various approaches used to produce new polyoxovanadate species, including heterometal-incorporated complexes of tetravanadates, hexavanadates, decavanadates and dodecavanadates. In particular, three types of synthetic routes are explored; based on i) coordination of metavanadate species to transition metal cations, ii) oxidation of reduced polyoxovanadates, and iii) template synthesis. Metavanadate species can coordinate to metal cations as inorganic macrocyclic ligands to form heteropolyoxovanadates. The incorporation of a heterometal cation into decavanadates has also been reported. The oxidation reaction of reduced polyoxovanadates provides a new route to the formation of the lacunary polyoxovanadates, which can serve as inorganic host molecules. Dodecavanadates are bowl-type molecules of particular structural interest; a chloride anion can be incorporated into the bowl through a template synthesis. Structural transformations between these dodecavanadate species and alkoxopolyoxovanadates are also described.

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“…The latter contains an oxidized anionic hexavanadate core adopting the Anderson structure. 4 The other reported examples of the hexavanadate clusters, [12][13][14] which are functionalized with tris(hydroxymethyl)alkane ligands, contain reduced {V 6 O 19 } cores which adopt the Linquist structure. 15…”

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confidence: 99%