2024
DOI: 10.3390/chemistry6060081
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Coordination Modes of Ortho-Substituted Benzoates Towards Divalent Copper Centres in the Presence of Diimines

Ioannis Loukas,
Eirini Frantzana,
Antonios Hatzidimitriou
et al.

Abstract: The coordination modes of several ortho-substituted benzoates towards the copper(II) centre are investigated. The coordination environment of the metal ion includes nitrogen atoms from 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen) and occasionally oxygen atoms from coordinated water, ethanol molecules, or nitrate ions. The compounds are investigated by a variety of spectroscopic methods and by single-crystal X-ray diffraction. Although the reaction scheme involved equimolar amounts of the reactants, cat… Show more

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