Coordination of Nickel(II) by 3‐(2‐(Diphenylphosphanyl)phenyl)‐1<i>H</i>‐pyrazole

We report the solution and structural chemistry of nickel(ii) complexes of the phosphine-oxime Ph2PC6H4-2-CH[double bond, length as m-dash]NOH (PCH[double bond, length as m-dash]NOH). PCH[double bond, length as m-dash]NOH invariably binds in a bidentate manner as illustrated by cis-Ni(PCH[double bond, length as m-dash]NOH)2Cl2 and cis-[Ni(PCH[double bond, length as m-dash]NOH)2]2+ (as its BF4- salt). Treatment of PCH[double bond, length as m-dash]NOH with Ni(OAc)2(H2O)4 gave charge-neutral trans-[Ni(PCH[double bond, length as m-dash]NO)2]0. Treatment of trans-[Ni(PCH[double bond, length as m-dash]NO)2]0 with BF3 gave [Ni(PCH[double bond, length as m-dash]NO)2BF2]BF4. The cation features a planar NiP2N2 center wherein the pair of oximate groups are linked by the difluoroboryl center. The 1 : 1 complexes of the oxime and the oximate are illustrated by [Ni(PCH[double bond, length as m-dash]NOH)Cl2]2 and [Ni(C6F5)(PCH[double bond, length as m-dash]NO)]2, which feature five- and four-coordinate Ni(ii) centers, respectively. All complexes in this series hydrolyze to give the trinickel oxo-phosphine-oximate complex [Ni3(PCH[double bond, length as m-dash]NO)3O]+. One feature of the PCH[double bond, length as m-dash]NOH ligand is its wide bite angle combined with its protic OH center. These aspects are manifested in the structures of Ni(PCH[double bond, length as m-dash]NOH)2Cl2 and [Ni(PCH[double bond, length as m-dash]NOH)Cl2]2, which show intramolecular hydrogen bonding to terminal chloride ligands.

show abstract

Ni(ii) complexes of the phosphine-oxime Ph₂PC₆H₄-2-CHNOH

Basu

Woods

Rauchfuss

2018

Dalton Trans.

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Coordination of Nickel(II) by 3‐(2‐(Diphenylphosphanyl)phenyl)‐1H‐pyrazole

Abstract: Abstract. Starting from easily accessible 3-[2-(diphenylphosphanyl)-phenyl]-1H-pyrazole a series of four-and five-coordinate diamagnetic nickel(II) complexes were synthesized and structurally characterized. The resulting complexes show dynamic NMR spectra reflecting a high

Cited by 1 publication

References 54 publications

Ni(ii) complexes of the phosphine-oxime Ph₂PC₆H₄-2-CHNOH

Ni(ii) complexes of the phosphine-oxime Ph₂PC₆H₄-2-CHNOH

Contact Info

Product

Resources

About

Coordination of Nickel(II) by 3‐(2‐(Diphenylphosphanyl)phenyl)‐1H‐pyrazole

Abstract: Abstract. Starting from easily accessible 3-[2-(diphenylphosphanyl)-phenyl]-1H-pyrazole a series of four-and five-coordinate diamagnetic nickel(II) complexes were synthesized and structurally characterized. The resulting complexes show dynamic NMR spectra reflecting a high

Cited by 1 publication

References 54 publications

Ni(ii) complexes of the phosphine-oxime Ph2PC6H4-2-CHNOH

Ni(ii) complexes of the phosphine-oxime Ph2PC6H4-2-CHNOH

Contact Info

Product

Resources

About

Ni(ii) complexes of the phosphine-oxime Ph₂PC₆H₄-2-CHNOH

Ni(ii) complexes of the phosphine-oxime Ph₂PC₆H₄-2-CHNOH