Coordination/Organometallic Compounds and Composites of Carbon Allotropes

Kharisov, Boris I.; Kharissova, Oxana V.

doi:10.1007/978-3-030-03505-1_7

Carbon Allotropes: Metal-Complex Chemistry, Properties and Applications 2019

DOI: 10.1007/978-3-030-03505-1_7

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Coordination/Organometallic Compounds and Composites of Carbon Allotropes

Boris I. Kharisov

Oxana V. Kharissova

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2021

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Cited by 2 publications

References 356 publications

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Recent progress in organometallic porphyrin‐based molecular materials for optical sensing, light conversion, and magnetic cooling

Ломова

2021

Applied Organom Chemis

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We present the review of fundamental parameters and properties of metalloporphyrins/phthalocyanines with axial covalent M-O/M-N bonds (M is a metal atom in the oxidation degree more than 2+) for use in the development of the chemistry of molecular materials. The porphyrin complexes covalently bonded along the axial axis are differed by the high oxidation state of a metal atom and related heightened axial reactivity compared with the corresponding derivatives of two charged metal cations, applications of which in both scientific studies and practical areas are most widely reflected in publications. The selection of chemical structures of the 3d, 4d, 5d, and 4f metal derivatives of porphyrins/phthalocyanines and study of their properties promising in the detection of bioactive organic bases, optoelectronics (active components of allsmall molecular organic solar cells), and spintronics (room-temperature magnetocaloric materials) are detailed in the article. The results of the first critical analysis of this topic in the review and the insight into chemical structure effects in the function of MPXs/MPcXs as molecular materials will contribute to further development of their organometallic chemistry.

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Recent progress in organometallic porphyrin‐based molecular materials for optical sensing, light conversion, and magnetic cooling

Ломова

2021

Applied Organom Chemis

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Dendrimeric and Corresponding Monometallic Iridium(III) Catalysts Bound to Carbon Nanotubes Used in Hydroamination Transformations

et al. 2021

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This report describes the synthesis of a carbon nanotube‐bound dendrimer and three carbon nanotube‐bound monometallic complexes and their use as catalysts. The polyamidoamine third generation dendrimer used here incorporates pyrazole‐triazole moieties suitable for ligating iridium(III) centres. The monometallic complexes use the same pyrazole‐triazole ligands coordinated to an iridium(III) centre. All catalysts were characterized using ICP‐AES and XPS to evaluate their metal loadings on the carbon surface with significantly higher relative weight percentage of iridium determined for the denrimeric species. The catalytic activity and practicality of the formed catalysts were tested using two different intramolecular hydroamination reactions.

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Coordination/Organometallic Compounds and Composites of Carbon Allotropes

Cited by 2 publications

References 356 publications

Recent progress in organometallic porphyrin‐based molecular materials for optical sensing, light conversion, and magnetic cooling

Recent progress in organometallic porphyrin‐based molecular materials for optical sensing, light conversion, and magnetic cooling

Dendrimeric and Corresponding Monometallic Iridium(III) Catalysts Bound to Carbon Nanotubes Used in Hydroamination Transformations

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