Coordination pillared layers using a dinuclear Mn(V) complex as a secondary building unit

Structures, Electrochemical and Spectral Properties of a Series of [MnN(CN)3(diimine)]– Complexes

“…The lack of evidence of hydrogen bonding with the terminal nitrido ligand of the anion implies that it has low nucleophilicity. This correlates with the short Mn≡N bond length [1.536(2) Å], which is comparable to those found in related complexes and coordination frameworks 22–25…”

A porous Mn(v) coordination framework with PtS topology: assessment of the influence of a terminal nitride on CO2 sorption

“…In the present study, the influence of a terminal nitride ligand on N 2 , H 10 and electrochemical 11 properties in the solution state by virtue of the active Mn(V) centre, and is known to give rise to unique thermal expansion 12 and gas sorption properties 13 when incorporated into framework materials. Frameworks with the PtS topology contain both square planar and tetrahedral nodes, and have been of interest for heterogeneous catalysis due to the presence of coordinatively unsaturated metal sites within their structures, examples of which have incorporated metalloporphyrins and post-synthetically modified ligands.…”

Guest-Tunable Excited States in a Cyanide-Bridged Luminescent Coordination Polymer

“…The guest-responsive nature of structures in the excited states of CdRe systems was examined further by TRIR. In the cyanide-bridged CPs, the structure in the ground states was evaluated by FT-IR spectroscopy because of the intense peak for CN – bonds. , Therefore, TRIR focusing on the stretching vibration of CN – groups helps elucidate the structural features of CdRe and CdRe’ in the excited states. The experiments were conducted at room temperature at 1 μs after excitation.…”