2005
DOI: 10.1016/j.jcat.2005.10.019
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Copper as a selective catalyst for the epoxidation of propene

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Cited by 179 publications
(107 citation statements)
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“…It is therefore reasonable to attempt the direct epoxidation of propene with molecular O 2 alone. Propene epoxidation with O 2 has been studied mainly with Cu and Ag catalysts [19][20][21][22][23][24], transition metal oxides [25][26][27][28][29], and molten salts [30][31][32][33]. Recently, Au catalysts were also investigated for this reaction over clusters (\2.0 nm) or tiny clusters (Au 6-10 ) [39,85,86].…”
Section: Gas-phase Propene Epoxidation With O 2 Alonementioning
confidence: 99%
See 1 more Smart Citation
“…It is therefore reasonable to attempt the direct epoxidation of propene with molecular O 2 alone. Propene epoxidation with O 2 has been studied mainly with Cu and Ag catalysts [19][20][21][22][23][24], transition metal oxides [25][26][27][28][29], and molten salts [30][31][32][33]. Recently, Au catalysts were also investigated for this reaction over clusters (\2.0 nm) or tiny clusters (Au 6-10 ) [39,85,86].…”
Section: Gas-phase Propene Epoxidation With O 2 Alonementioning
confidence: 99%
“…Several types of catalysts have been investigated, for example Cu and Ag catalysts [19][20][21][22][23][24], transition metal oxides [25][26][27][28][29] and molten salts [30][31][32][33].…”
Section: Introductionmentioning
confidence: 99%
“…In terms of TOF, our systems show values over 10 h -1 which compare to some Agbased systems [13], but would be below the data reported by Lei et al [62] It must be noted, however, that mass spectrometry was used to analyze the reaction products which raises some questions concerning the selectivity of the prepared systems. The use of Cu-based systems, on the other hand has resulted in comparatively poorer TOF values [63]. In terms of conversion and selectivity, Cu-based catalysts seem to perform similarly to our systems (see for example) but the reported systems contain a significant loading of Ruthenium oxide, which is comparatively expensive.…”
Section: Propylene Epoxidation Reactionmentioning
confidence: 71%
“…Several studies in the literature focused on the active oxidation state of Cu in epoxidation reactions. Vaughan et al proposed that Cu 0 species in highly dispersed atomic-like form are the active sites in epoxidation [33]. On the other hand, Zhu et al …”
Section: Introductionmentioning
confidence: 99%